ForMatter/Finishes/patina/Ferric chloride etch / patina (copper, brass)
finish_patina_ferric_etch

Ferric chloride etch / patina (copper, brass)

patina · patinated · ferric etch, PCB etch, salt-print copper

Ferric chloride dissolves copper and brass selectively — covered areas resist (resist patterns are how PCBs and intaglio plates work). Left to dwell, the surface goes through warm rust-brown into a soft, deeply textured patina. Used by jewelers, printmakers, hobbyist circuit-builders.

FeCl₃ in aqueous solution (~40% Baumé) etches copper at 25–50 °C, ~1 µm/min. Reaction: 2 FeCl₃ + Cu → CuCl₂ + 2 FeCl₂. Protected (resist-coated) regions remain at original surface; exposed regions deepen and texture. Long dwell times produce CuCl₂ + Fe(OH)₃ residues that give the warm rust-brown patina look. Standard PCB-etchant; in jewelry / metalsmithing used for relief texture and color.

character — warm copper-brown to ruddy, soft texture in etched zones, recess-shadow contrast.

Finish properties

  • levelpatinated
  • subcategorychloride etch + corrosion residue
  • applies tometal

Second life

reversibilitymoderate — patinas can be stripped (acid, mechanical polishing) and re-applied; the substrate metal is preserved through the process. The historical patina cannot be exactly reproduced after stripping.
blocks substrate recyclingno
renewabilityfield-renewable — a patina can be refreshed or applied to a stripped piece by a metalsmith with the right chemistry. Conservation-grade re-patination is a specialty (Sculpture Conservation Studio practice).

Hughes & Rowe *The Colouring, Bronzing and Patination of Metals* (Crafts Council, 1991, Watson-Guptill ed. 1995); American Institute for Conservation patina-conservation guidelines.

Citations